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We examine the arsenic distribution and its influence on dopant activation in poly-crystalline CdTe1−xSex solar cell absorbers prepared by vapor transport deposition followed by CdCl2 annealing. For as-deposited CdTe:As, local-electrode atom probe (LEAP) tomography reveals non-uniform distributions of arsenic clusters in the top “doped” layers. Following CdCl2 annealing, secondary ion mass spectrometry suggests that arsenic has diffused into the entire CdTe layer, while LEAP tomography reveals dissolution of the clusters, with nearly uniform distribution of arsenic atoms in CdTe. Since the arsenic fraction (fAs) is 1 × 1018 cm−3, but the hole density ranges from 7.5 to 9.5 × 1015 cm−3, we hypothesize that a large fraction of the arsenic has been incorporated into interstitial sites or cadmium substitutional sites, resulting in limited dopant activation. 

Abstract Earth's tropics are characterized by quasi‐steady precipitation with small oscillations about a mean value, which has led to the hypothesis that moist convection is in a state of quasi‐equilibrium (QE). In contrast, very warm simulations of Earth's tropical convection are characterized by relaxation‐oscillator‐like (RO) precipitation, with short‐lived convective storms and torrential rainfall forming and dissipating at regular intervals with little to no precipitation in between. We develop a model of moist convection by combining a zero‐buoyancy model of bulk‐plume convection with a QE heat engine model, and we use it to show that QE is violated at high surface temperatures. We hypothesize that the RO state emerges when the equilibrium condition of the convective heat engine is violated, that is, when the heating rate times a thermodynamic efficiency exceeds the rate at which work can be performed. We test our hypothesis against one‐ and three‐dimensional numerical simulations and find that it accurately predicts the onset of RO convection. The proposed mechanism for RO emergence from QE breakdown is agnostic of the condensable, and can be applied to any planetary atmosphere undergoing moist convection. To date, RO states have only been demonstrated in three‐dimensional convection‐resolving simulations, which has made it seem that the physics of the RO state requires simulations that can explicitly resolve the three‐dimensional interaction of cloudy plumes and their environment. We demonstrate that RO states also exist in single‐column simulations of radiative‐convective equilibrium with parameterized convection, albeit in a different surface temperature range and with much longer storm‐free intervals. 

Intertwined charge and spin correlations are ubiquitous in a wide range of transition metal oxides and are often perceived as intimately related to unconventional superconductivity. Theoretically envisioned as driven by strong electronic correlations, the intertwined order is usually found to be strongly coupled to the lattice as signaled by pronounced phonon softening. Recently, both charge and spin density waves (CDW and SDW) and superconductivity have been discovered in several Ruddlesden-Popper (RP) nickelates, in particular trilayer nickelates $R{E}_4{\mathrm{Ni}}_3{\mathrm{O}}_{10}$( $RE=\mathrm{Pr}$, La). The nature of the intertwined order and the role of lattice-charge coupling are at the heart of the debate about these materials. Using inelastic x-ray scattering, we mapped the low-energy phonon dispersions in $R{E}_4{\mathrm{Ni}}_3{\mathrm{O}}_{10}$and found no evidence of softening near the CDW wave vector over a wide temperature range, which contrasts with the pronounced anomalies frequently observed in cuprate superconductors. Calculations of the electronic susceptibility revealed a peak at the observed SDW ordering vector but not at the CDW wave vector. Our experimental and theoretical findings highlight the crucial role of the spin degree of freedom and establish a foundation for understanding the interplay between superconductivity and density-wave transitions in RP nickelate superconductors and beyond. 

Beta-propeller Protein Associated Neurodegeneration (BPAN) is a devastating neurodevelopmental and neurodegenerative disease linked to variants inWDR45. Currently, there is no cure or disease altering treatment for this disease. This is, in part, due to a lack of insight into early phenotypes of BPAN progression andWDR45’s role in establishing and maintaining neurological function. Here we generated and characterized a mouse model bearing a c52C > T BPAN patient variant inWdr45.We show this mutation ablatesWDR45protein expression and alters autophagy in the brain. Behavioral analysis of these mice revealed characteristic signs of BPAN including cognitive impairment, hyperactivity, and motor decline. We show these behaviors coincide with widespread glial activation and early development of axonal spheroids in multiple neuron subclasses throughout the brain. Several lines of evidence suggest these spheroids arise from axon terminals. Transcriptomic analysis uncovered multiple disrupted pathways in the cortex including genes associated with synapses, neurites, endosomes, endoplasmic reticulum, and ferroptosis. This is supported by accumulation of the iron regulating transferrin receptor 1 (TFRC) and the endoplasmic reticulum resident calreticulin (CALR) in the cortex as these animals age. CALR forms spheroid structures similar to the axonal spheroids seen in these animals. Taken together, our data suggest that WDR45 is necessary for healthy brain function and maintenance of axon terminals. This model opens the door to therapeutics targeting BPAN and further exploration of the role of WDR45 in neuronal function. 

Abstract Aqueous‐phase uptake and processing of water‐soluble organic compounds can promote secondary organic aerosol (SOA) production. We evaluated the contributions of aqueous‐phase chemistry to summertime urban SOA at two sites in New York City. The relative role of aqueous‐phase processing varied with chemical and environmental conditions, with evident daytime SOA enhancements (e.g., >1 μg/m³) during periods with relative humidities (RH) exceeding 65% and often higher temperatures. Oxygenated organic aerosol (OOA) production was also sensitive to secondary inorganic aerosols, in part through their influence on aerosol liquid water. On average, high‐RH periods exhibited a 69% increase in less‐oxidized OOA production in Queens, NY. These enhancements coincided with southerly backward trajectories and greater inorganic aerosol concentrations, yet showed substantial intra‐city variability between Queens and Manhattan. The observed aqueous‐phase SOA production, even with historically low sulfate and nitrate aerosol loadings, highlights both opportunities and challenges for continued reductions in summertime PM_2.5in urban communities.